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D. A. Singleton · SciRah

Researcher profile · Semantic Scholar

D. A. Singleton

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D. A. Singleton — researcher profile on SciRah

h-index: 43
Works: 150
Citations: 6,004

Most-cited papers

A Case Study of the Mechanism of Alcohol-Mediated Morita Baylis–Hillman Reactions. The Importance of Experimental Observations
R. E. Plata, D. A. Singleton
2015Journal of the American Chemical Society362 citations Open access
Semantic Scholar
High-Precision Simultaneous Determination of Multiple Small Kinetic Isotope Effects at Natural Abundance
D. A. Singleton, Allen A. Thomas
1995294 citations
Semantic Scholar
Mechanism of ene reactions of singlet oxygen. A two-step no-intermediate mechanism.
D. A. Singleton, C. Hang, M. Szymanski, M. P. Meyer +6 more
2003Journal of the American Chemical Society225 citations
Semantic Scholar
Phenomenon of optical self-purification of chiral non-racemic compounds.
V. Soloshonok, Hisanori Ueki, Manabu Yasumoto, Shekar Mekala +2 more
2007Journal of the American Chemical Society163 citations
Semantic Scholar
Dynamic effects on the periselectivity, rate, isotope effects, and mechanism of cycloadditions of ketenes with cyclopentadiene.
Bryson R Ussing, C. Hang, D. A. Singleton
2006Journal of the American Chemical Society162 citations Open access
Semantic Scholar
Experimental and Theoretical Kinetic Isotope Effects for Asymmetric Dihydroxylation. Evidence Supporting a Rate-Limiting “(3 + 2)” Cycloaddition
A. DelMonte, J. Haller, K. Houk, K. Sharpless +3 more
1997154 citations
Semantic Scholar
Outer-Sphere Direction in Iridium C-H Borylation
Philipp C. Roosen, Venkata A. Kallepalli, B. Chattopadhyay, D. A. Singleton +2 more
2012Journal of the American Chemical Society140 citations Open access
Semantic Scholar
Control Elements in Dynamically-Determined Selectivity on a Bifurcating Surface
Jacqueline B. Thomas, Jack R. Waas, M. Harmata, D. A. Singleton
2008Journal of the American Chemical Society131 citations Open access
Semantic Scholar
Dynamics and the Failure of Transition State Theory in Alkene Hydroboration
Yatsandra Oyola, D. A. Singleton
2009Journal of the American Chemical Society123 citations Open access
Semantic Scholar
Dynamically Complex [6+4] and [4+2] Cycloadditions in the Biosynthesis of Spinosyn A
Ashay Patel, Zhuo Chen, Zhongyue Yang, O. Gutierrez +3 more
2016Journal of the American Chemical Society121 citations Open access
Semantic Scholar
Synchronous or Asynchronous? An “Experimental” Transition State from a Direct Comparison of Experimental and Theoretical Kinetic Isotope Effects for a Diels−Alder Reaction
Brett R. Beno, K. Houk, D. A. Singleton
1996121 citations
Semantic Scholar
Ir-Catalyzed ortho-Borylation of Phenols Directed by Substrate–Ligand Electrostatic Interactions: A Combined Experimental/in Silico Strategy for Optimizing Weak Interactions
B. Chattopadhyay, Jonathan E. Dannatt, Ivonne L. Andujar-De Sanctis, Kristin A Gore +3 more
2017Journal of the American Chemical Society118 citations Open access
Semantic Scholar
Isotope effects and the nature of selectivity in rhodium-catalyzed cyclopropanations.
D. Nowlan, T. Gregg, H. Davies, D. A. Singleton
2003Journal of the American Chemical Society116 citations
Semantic Scholar
Electronic effects in iridium C–H borylations: insights from unencumbered substrates and variation of boryl ligand substituents
Britt A. Vanchura, Sean M. Preshlock, Philipp C. Roosen, Venkata A. Kallepalli +4 more
2010Chemical Communications112 citations Open access
Semantic Scholar
Recrossing and Dynamic Matching Effects on Selectivity in a Diels-Alder Reaction
Zhi-Hong Wang, Jennifer S. Hirschi, D. A. Singleton
2009Angewandte Chemie102 citations Open access
Semantic Scholar
Reinvestigation of the Isotope Effects for the Claisen and Aromatic Claisen Rearrangements: The Nature of the Claisen Transition States
M. P. Meyer, A. DelMonte, D. A. Singleton
1999102 citations
Semantic Scholar
A few molecules can control the enantiomeric outcome. Evidence supporting absolute asymmetric synthesis using the Soai asymmetric autocatalysis.
D. A. Singleton, L. Vo
2003Organic Letters100 citations
Semantic Scholar
"Concerted" transition state, stepwise mechanism. Dynamics effects in C2-C6 enyne allene cyclizations.
T. Bekele, Chad F. Christian, M. Lipton, D. A. Singleton
2005Journal of the American Chemical Society99 citations Open access
Semantic Scholar
Experimental Geometry of the Epoxidation Transition State
D. A. Singleton, S. R. Merrigan, Jian Liu, K. Houk
199798 citations
Semantic Scholar
A new form of kinetic isotope effect. Dynamic effects on isotopic selectivity and regioselectivity.
D. A. Singleton, C. Hang, M. Szymanski, Erin E. Greenwald
2003Journal of the American Chemical Society90 citations
Semantic Scholar
Enantioselective synthesis without discrete optically active additives.
D. A. Singleton, L. Vo
2002Journal of the American Chemical Society90 citations
Semantic Scholar
Experimental Evidence for Heavy-Atom Tunneling in the Ring-Opening of Cyclopropylcarbinyl Radical from Intramolecular 12C/13C Kinetic Isotope Effects
Ollie M Gonzalez-James, Xue Zhang, A. Datta, D. Hrovat +2 more
2010Journal of the American Chemical Society82 citations Open access
Semantic Scholar
Entropic Intermediates and Hidden Rate-Limiting Steps in Seemingly Concerted Cycloadditions. Observation, Prediction, and Origin of an Isotope Effect on Recrossing
Ollie M Gonzalez-James, Eugene E. Kwan, D. A. Singleton
2012Journal of the American Chemical Society80 citations Open access
Semantic Scholar
13C Kinetic Isotope Effects for the Addition of Lithium Dibutylcuprate to Cyclohexenone. Reductive Elimination Is Rate-Determining
D. Frantz, D. A. Singleton, J. P. Snyder
199774 citations
Semantic Scholar
Insights into the mechanism of flavoprotein-catalyzed amine oxidation from nitrogen isotope effects on the reaction of N-methyltryptophan oxidase.
Erik C. Ralph, Jennifer S. Hirschi, Mark A. Anderson, W. Cleland +2 more
2007Biochemistry72 citations Open access
Semantic Scholar
Dynamics and the Regiochemistry of Nitration of Toluene
Yexenia Nieves-Quinones, D. A. Singleton
2016Journal of the American Chemical Society67 citations Open access
Semantic Scholar
Isotope Effects, Dynamic Matching, and Solvent Dynamics in a Wittig Reaction. Betaines as Bypassed Intermediates
Zhuo Chen, Yexenia Nieves-Quinones, Jack R. Waas, D. A. Singleton
2014Journal of the American Chemical Society66 citations Open access
Semantic Scholar
Simultaneous Determination of Intermolecular and Intramolecular 13C and 2H Kinetic Isotope Effects at Natural Abundance
D. A. Singleton, M. Szymanski
199966 citations
Semantic Scholar
Isotope effects and the distinction between synchronous, asynchronous, and stepwise Diels–Alder reactions
D. A. Singleton, Brian E. Schulmeier, C. Hang, Allen A. Thomas +2 more
200164 citations
Semantic Scholar
Dynamic Origin of the Stereoselectivity of a Nucleophilic Substitution Reaction
Xavier S Bogle, D. A. Singleton
2012Organic Letters60 citations Open access
Semantic Scholar
Dynamics and a Unified Understanding of Competitive [2,3]- and [1,2]-Sigmatropic Rearrangements Based on a Study of Ammonium Ylides
B. Biswas, Sean Collins, D. A. Singleton
2014Journal of the American Chemical Society58 citations Open access
Semantic Scholar
Isotope effects and the nature of enantioselectivity in the shi epoxidation. The importance of asynchronicity.
D. A. Singleton, Zhi-Hong Wang
2005Journal of the American Chemical Society58 citations
Semantic Scholar
Newtonian Kinetic Isotope Effects. Observation, Prediction, and Origin of Heavy-Atom Dynamic Isotope Effects
K. K. Kelly, Jennifer S. Hirschi, D. A. Singleton
2009Journal of the American Chemical Society55 citations Open access
Semantic Scholar
Transition State Geometry Measurements from 13C Isotope Effects. The Experimental Transition State for the Epoxidation of Alkenes with Oxaziridines
Jennifer S. Hirschi, Tetsuya Takeya, C. Hang, D. A. Singleton
2009Journal of the American Chemical Society50 citations Open access
Semantic Scholar
Controlling Selectivity by Controlling the Path of Trajectories
B. Biswas, D. A. Singleton
2015Journal of the American Chemical Society49 citations Open access
Semantic Scholar
Isotope Effects and the Mechanism of Chlorotrimethylsilane-Mediated Addition of Cuprates to Enones
D. Frantz, D. A. Singleton
200049 citations
Semantic Scholar
Experimental Proof of the Non-Least-Motion Cycloadditions of Dichlorocarbene to Alkenes: Kinetic Isotope Effects and Quantum Mechanical Transition States
A. Keating, S. R. Merrigan, D. A. Singleton, K. N. Houk
199949 citations
Semantic Scholar
Mechanism and origin of enantioselectivity in the Rh2(OAc)(DPTI)3-catalyzed cyclopropenation of alkynes.
D. Nowlan, D. A. Singleton
2005Journal of the American Chemical Society46 citations Open access
Semantic Scholar
Competition between Reaction and Intramolecular Energy Redistribution in Solution. Observation and Nature of Nonstatistical Dynamics in the Ozonolysis of Vinyl Ethers
L. M. M. Quijano, D. A. Singleton
2011Journal of the American Chemical Society45 citations Open access
Semantic Scholar
Solvation Dynamics and the Nature of Reaction Barriers and Ion-Pair Intermediates in Carbocation Reactions
V. A. Roytman, D. A. Singleton
2020Journal of the American Chemical Society43 citations Open access
Semantic Scholar
Isotope effects and the nature of stereo- and regioselectivity in hydroaminations of vinylarenes catalyzed by palladium(ii)-diphosphine complexes.
L. Vo, D. A. Singleton
2004Organic Letters41 citations
Semantic Scholar
Isotope Effects and the Mechanism of Atom Transfer Radical Polymerization
D. A. Singleton, D. Nowlan, Nazeem Jahed, K. Matyjaszewski
200341 citations
Semantic Scholar
13C Kinetic Isotope Effects and the Mechanism of the Uncatalyzed Decarboxylation of Orotic Acid
D. A. Singleton, S. R. Merrigan, B. Kim, P. Beak +2 more
200040 citations
Semantic Scholar
Isotope effects and the mechanism of allylic hydroxylation of alkenes with selenium dioxide.
D. A. Singleton, C. Hang
2000Journal of Organic Chemistry39 citations
Semantic Scholar
Failure and Redemption of Statistical and Nonstatistical Rate Theories in the Hydroboration of Alkenes
Johnathan O. Bailey, D. A. Singleton
2017Journal of the American Chemical Society37 citations Open access
Semantic Scholar
Concert along the Edge. Dynamics and the Nature of the Border between General and Specific Acid-Base Catalysis
Hannah R. Aziz, D. A. Singleton
2017Journal of the American Chemical Society37 citations Open access
Semantic Scholar
Deuterium kinetic isotope effects and the mechanism of the bacterial luciferase reaction.
W. Francisco, H. Abu-Soud, A. DelMonte, D. A. Singleton +2 more
1998Biochemistry37 citations
Semantic Scholar
Isotope effects and the mechanism of an electron-transfer-catalyzed Diels-Alder reaction.
N. Saettel, O. Wiest, D. A. Singleton, M. P. Meyer
2002Journal of the American Chemical Society35 citations
Semantic Scholar
Isotope Effects and Heavy-Atom Tunneling in the Roush Allylboration of Aldehydes
Mathew J. Vetticatt, D. A. Singleton
2012Organic Letters33 citations Open access
Semantic Scholar
Resolution of Conflicting Mechanistic Observations in Ester Aminolysis. A Warning on the Qualitative Prediction of Isotope Effects for Reactive Intermediates
D. A. Singleton, S. R. Merrigan
200032 citations
Semantic Scholar

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C. Hang×6
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C. Hang — researcher profile on SciRah
Jennifer S. Hirschi×5
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S. R. Merrigan×5
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Allen A. Thomas×3
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M. Szymanski — researcher profile on SciRah

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M. P. Meyer — researcher profile on SciRah

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A. DelMonte — researcher profile on SciRah

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K. Houk — researcher profile on SciRah

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D. Nowlan — researcher profile on SciRah

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L. Vo — researcher profile on SciRah