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M. Suginome · SciRah

Researcher profile · Semantic Scholar

M. Suginome

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M. Suginome — researcher profile on SciRah

h-index: 58
Works: 364
Citations: 10K

Most-cited papers

Inversion or retention? Effects of acidic additives on the stereochemical course in enantiospecific Suzuki-Miyaura coupling of α-(acetylamino)benzylboronic esters.
Tomotsugu Awano, Toshimichi Ohmura, M. Suginome
2011Journal of the American Chemical Society153 citations
Semantic Scholar
Regioselective synthesis of 1,2-dihydropyridines by rhodium-catalyzed hydroboration of pyridines.
K. Oshima, Toshimichi Ohmura, M. Suginome
2012Journal of the American Chemical Society132 citations
Semantic Scholar
Solvent-dependent switch of helical main-chain chirality in sergeants-and-soldiers-type poly(quinoxaline-2,3-diyl)s: effect of the position and structures of the "sergeant" chiral units on the screw-sense induction.
Yuuya Nagata, Tetsuya Yamada, Takumi Adachi, Yuto Akai +2 more
2013Journal of the American Chemical Society109 citations
Semantic Scholar
Enhanced catalyst activity and enantioselectivity with chirality-switchable polymer ligand PQXphos in Pd-catalyzed asymmetric silaborative cleavage of meso-methylenecyclopropanes.
Yuto Akai, Takeshi Yamamoto, Yuuya Nagata, Toshimichi Ohmura +1 more
2012Journal of the American Chemical Society107 citations
Semantic Scholar
Catalytic functionalization of methyl group on silicon: iridium-catalyzed C(sp3)-H borylation of methylchlorosilanes.
Toshimichi Ohmura, Takeru Torigoe, M. Suginome
2012Journal of the American Chemical Society91 citations
Semantic Scholar
Solid polymer films exhibiting handedness-switchable, full-color-tunable selective reflection of circularly polarized light.
Yuuya Nagata, Keisuke Takagi, M. Suginome
2014Journal of the American Chemical Society86 citations
Semantic Scholar
Majority-Rules-Type Helical Poly(quinoxaline-2,3-diyl)s as Highly Efficient Chirality-Amplification Systems for Asymmetric Catalysis.
Yuan-Zhen Ke, Yuuya Nagata, Tetsuya Yamada, M. Suginome
2015Angewandte Chemie81 citations
Semantic Scholar
Single-Handed Helical Poly(quinoxaline-2,3-diyl)s Bearing Achiral 4-Aminopyrid-3-yl Pendants as Highly Enantioselective, Reusable Chiral Nucleophilic Organocatalysts in the Steglich Reaction.
Takeshi Yamamoto, R. Murakami, M. Suginome
2017Journal of the American Chemical Society77 citations
Semantic Scholar
Anthranilamide: a simple, removable ortho-directing modifier for arylboronic acids serving also as a protecting group in cross-coupling reactions.
H. Ihara, Masashi Koyanagi, M. Suginome
2011Organic Letters77 citations
Semantic Scholar
Chirality-switchable circularly polarized luminescence in solution based on the solvent-dependent helix inversion of poly(quinoxaline-2,3-diyl)s.
Yuuya Nagata, T. Nishikawa, M. Suginome
2014Chemical Communications72 citations
Semantic Scholar
Poly(quinoxaline-2,3-diyl) as a Multifunctional Chiral Scaffold for Circularly Polarized Luminescent Materials: Color Tuning, Energy Transfer, and Switching of the CPL Handedness.
T. Nishikawa, Yuuya Nagata, M. Suginome
2017ACS Macro Letters71 citations
Semantic Scholar
Poly(quinoxaline-2,3-diyl)s bearing (S)-3-octyloxymethyl side chains as an efficient amplifier of alkane solvent effect leading to switch of main-chain helical chirality.
Yuuya Nagata, T. Nishikawa, M. Suginome
2014Journal of the American Chemical Society71 citations
Semantic Scholar
Chiral palladacycle catalysts generated on a single-handed helical polymer skeleton for asymmetric arylative ring opening of 1,4-epoxy-1,4-dihydronaphthalene.
Takeshi Yamamoto, Yuto Akai, M. Suginome
2014Angewandte Chemie71 citations
Semantic Scholar
Exerting control over the helical chirality in the main chain of sergeants-and-soldiers-type poly(quinoxaline-2,3-diyl)s by changing from random to block copolymerization protocols.
Yuuya Nagata, T. Nishikawa, M. Suginome
2015Journal of the American Chemical Society70 citations
Semantic Scholar
Asymmetric Catalysis in Chiral Solvents: Chirality Transfer with Amplification of Homochirality through a Helical Macromolecular Scaffold
Yuuya Nagata, R. Takeda, M. Suginome
2019ACS Central Science68 citations Open access
Semantic Scholar
Chirality-Amplifying, Dynamic Induction of Single-Handed Helix by Chiral Guests to Macromolecular Chiral Catalysts Bearing Boronyl Pendants as Receptor Sites.
Takeshi Yamamoto, R. Murakami, Satoko Komatsu, M. Suginome
2018Journal of the American Chemical Society57 citations
Semantic Scholar
Dearomatizing conversion of pyrazines to 1,4-dihydropyrazine derivatives via transition-metal-free diboration, silaboration, and hydroboration.
K. Oshima, Toshimichi Ohmura, M. Suginome
2012Chemical Communications53 citations
Semantic Scholar
Organocatalytic diboration involving "reductive addition" of a boron-boron σ-bond to 4,4'-bipyridine.
Toshimichi Ohmura, Yohei Morimasa, M. Suginome
2015Journal of the American Chemical Society52 citations
Semantic Scholar
Catalytic asymmetric synthesis using chirality-switchable helical polymer as a chiral ligand
M. Suginome, Takeshi Yamamoto, Yuuya Nagata, Tetsuya Yamada +1 more
201250 citations Open access
Semantic Scholar
4,4'-Bipyridyl-Catalyzed Reduction of Nitroarenes by Bis(neopentylglycolato)diboron.
Hiromu Hosoya, Luis C. Misal Castro, I. Sultan, Y. Nakajima +5 more
2019Organic Letters47 citations
Semantic Scholar
Solvent Effect on the Sergeants-and-Soldiers Effect Leading to Bidirectional Induction of Single-Handed Helical Sense of Poly(quinoxaline-2,3-diyl)s Copolymers in Aromatic Solvents.
Yuuya Nagata, T. Nishikawa, M. Suginome
2016ACS Macro Letters47 citations Open access
Semantic Scholar
Functionalization of tetraorganosilanes and permethyloligosilanes at a methyl group on silicon via iridium-catalyzed C(sp3)-H borylation
Toshimichi Ohmura, Takeru Torigoe, M. Suginome
201346 citations
Semantic Scholar
Elucidating the Solvent Effect on the Switch of the Helicity of Poly(quinoxaline-2,3-diyl)s: A Conformational Analysis by Small-Angle Neutron Scattering.
Yuuya Nagata, T. Nishikawa, M. Suginome, S. Sato +5 more
2018Journal of the American Chemical Society43 citations Open access
Semantic Scholar
Three-Way-Switchable (Right/Left/OFF) Selective Reflection of Circularly Polarized Light on Solid Thin Films of Helical Polymer Blends.
Yuuya Nagata, Makoto Uno, M. Suginome
2016Angewandte Chemie38 citations
Semantic Scholar
Boryl-Directed, Ir-Catalyzed C(sp3)-H Borylation of Alkylboronic Acids Leading to Site-Selective Synthesis of Polyborylalkanes.
Takeshi Yamamoto, A. Ishibashi, M. Suginome
2019Organic Letters32 citations
Semantic Scholar
Site- and Regioselective Silaborative C–C Cleavage of 1-Alkyl-2-Methylenecyclopropanes Using a Platinum Catalyst with a Sterically Demanding Silylboronic Ester
Toshimichi Ohmura, Hiroki Taniguchi, M. Suginome
201531 citations
Semantic Scholar
Anthranilamide-masked o-Iodoarylboronic Acids as Coupling Modules for Iterative Synthesis of ortho-Linked Oligoarenes
Masashi Koyanagi, Nils C. Eichenauer, H. Ihara, Takeshi Yamamoto +1 more
201331 citations
Semantic Scholar
(E)- and (Z)-β-borylallylsilanes by alkyne silaboration followed by regio- and stereoselective double-bond migration.
Toshimichi Ohmura, K. Oshima, M. Suginome
2011Angewandte Chemie29 citations
Semantic Scholar
Regioselective Synthesis of o-Benzenediboronic Acids via Ir-Catalyzed o-C-H Borylation Directed by a Pyrazolylaniline-Modified Boronyl Group.
Takeshi Yamamoto, A. Ishibashi, M. Suginome
2017Organic Letters28 citations
Semantic Scholar
Synthesis and Catalytic Applications of a Triptycene-Based Monophosphine Ligand for Palladium-Mediated Organic Transformations
Franco King-Chi Leung, Fumitaka Ishiwari, Yoshiaki Shoji, T. Nishikawa +6 more
2017ACS Omega27 citations Open access
Semantic Scholar
Poly(quinoxaline-2,3-diyl)s: A Fascinating Helical Macromolecular Scaffold for New Chiral Functions
M. Suginome, Takeshi Yamamoto, Yuuya Nagata
201526 citations Open access
Semantic Scholar
Pyridine‐Based Organocatalysts for Regioselective syn ‐1,2‐Silaboration of Terminal Alkynes and Allenes
Yohei Morimasa, K. Kabasawa, Toshimichi Ohmura, M. Suginome
2019Asian Journal of Organic Chemistry25 citations
Semantic Scholar
Asymmetric Cycloisomerization of o-Alkenyl-N-Methylanilines to Indolines by Iridium-Catalyzed C(sp3 )-H Addition to Carbon-Carbon Double Bonds.
Takeru Torigoe, Toshimichi Ohmura, M. Suginome
2017Angewandte Chemie25 citations
Semantic Scholar
Asymmetric Suzuki-Miyaura cross-coupling of 1-bromo-2-naphthoates using the helically chiral polymer ligand PQXphos.
Yuto Akai, Laure Konnert, Takeshi Yamamoto, M. Suginome
2015Chemical Communications25 citations
Semantic Scholar
Nickel‐Catalyzed Cyclizative trans‐Carboboration of Alkynes through Activation of Boron–Chlorine Bonds by Using Organometallic Reagents as Donors of Organic Groups
Masaki Daini, A. Yamamoto, M. Suginome
201325 citations
Semantic Scholar
Chirality-Switchable 2,2'-Bipyridine Ligands Attached to Helical Poly(quinoxaline-2,3-diyl)s for Copper-Catalyzed Asymmetric Cyclopropanation of Alkenes.
Yukako Yoshinaga, Takeshi Yamamoto, M. Suginome
2017ACS Macro Letters24 citations
Semantic Scholar
Complementary Induction of Right- and Left-Handed Helical Structures by the Positioning of Chiral Groups on the Monomer Units: Introduction of (-)-Menthol as Side Chains of Poly(quinoxaline-2,3-diyl)s.
Takeshi Yamamoto, Takumi Adachi, M. Suginome
2013ACS Macro Letters24 citations
Semantic Scholar
Catalytic Generation of Rhodium Silylenoid for Alkene-Alkyne-Silylene [2 + 2 + 1] Cycloaddition.
Toshimichi Ohmura, Ikuo Sasaki, M. Suginome
2019Organic Letters23 citations Open access
Semantic Scholar
Ether solvent-induced chirality inversion of helical poly(quinoxaline-2,3-diyl)s containing L-lactic acid derived side chains
Yuuya Nagata, Takuma Kuroda, Keisuke Takagi, M. Suginome
201423 citations
Semantic Scholar
Construction of Silicon-Containing Seven-Membered Rings by Catalytic [4 + 2 + 1] Cycloaddition through Rhodium Silylenoid.
Ikuo Sasaki, Toshimichi Ohmura, M. Suginome
2020Organic Letters22 citations Open access
Semantic Scholar
Utilization of a Trimethylsilyl Group as a Synthetic Equivalent of a Hydroxyl Group via Chemoselective C(sp3)-H Borylation at the Methyl Group on Silicon.
Takeru Torigoe, Toshimichi Ohmura, M. Suginome
2017Journal of Organic Chemistry22 citations
Semantic Scholar
Iridium-catalysed borylation of sterically hindered C(sp³)-H bonds: remarkable rate acceleration by a catalytic amount of potassium tert-butoxide.
Toshimichi Ohmura, Takeru Torigoe, M. Suginome
2014Chemical Communications22 citations
Semantic Scholar
Cycloaddition-based formal C-H alkynylation of isoindoles leading to the synthesis of air-stable fluorescent 1,3-dialkynylisoindoles.
Toshimichi Ohmura, Akihito Kijima, Yusuke Komori, M. Suginome
2013Organic Letters22 citations
Semantic Scholar
Pressure-dependent helix inversion of poly(quinoxaline-2,3-diyl)s containing chiral side chains in non-aqueous solvents.
Yuuya Nagata, R. Takeda, M. Suginome
2015Chemical Communications19 citations Open access
Semantic Scholar
Enantiospecific Suzuki-Miyaura Coupling of Nonbenzylic α-(Acylamino)alkylboronic Acid Derivatives.
Toshimichi Ohmura, K. Miwa, Tomotsugu Awano, M. Suginome
2018Chemistry - An Asian Journal18 citations
Semantic Scholar
4,4′-Bipyridine-catalyzed Stereoselective trans-Diboration of Acetylenedicarboxylates to 2,3-Diborylfumarates
Toshimichi Ohmura, Yohei Morimasa, M. Suginome
201718 citations
Semantic Scholar
Iridium-Catalyzed Intramolecular Methoxy C-H Addition to Carbon-Carbon Triple Bonds: Direct Synthesis of 3-Substituted Benzofurans from o-Methoxyphenylalkynes.
Takeru Torigoe, Toshimichi Ohmura, M. Suginome
2016Chemistry18 citations
Semantic Scholar
Stereoinvertive C-C Bond Formation at the Boron-Bound Stereogenic Centers via Copper-Bipyridine-Catalyzed Intramolecular Coupling of α-Aminobenzylboronic Esters.
Yukako Yoshinaga, Takeshi Yamamoto, M. Suginome
2020Angewandte Chemie17 citations
Semantic Scholar
Enantioconvergent Cu-Catalyzed Intramolecular C-C Coupling at Boron-Bound C(sp3) Atoms of α-Aminoalkylboronates Using a C1-Symmetrical 2,2'-Bipyridyl Ligand Attached to a Helically Chiral Macromolecular Scaffold.
Yukako Yoshinaga, Takeshi Yamamoto, M. Suginome
2020Journal of the American Chemical Society16 citations
Semantic Scholar
Synthesis and Solution Properties of a Rigid Helical Star Polymer: Three-Arm Star Poly(quinoxaline-2,3-diyl)
H. Hasegawa, Yuuya Nagata, Ken Terao, M. Suginome
201716 citations Open access
Semantic Scholar

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Toshimichi Ohmura×20
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Toshimichi Ohmura — researcher profile on SciRah
Yuuya Nagata×18
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Yuuya Nagata — researcher profile on SciRah
Takeshi Yamamoto×15
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T. Nishikawa×7
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Yohei Morimasa×3

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Tomotsugu Awano×2

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