Vladimir K. Dioumaev

Most-cited papers

1. Low-Valent Ruthenium Complexes of the Non-innocent 2,6-Bis(imino)pyridine Ligand

   M. Gallagher, Noah L. Wieder, Vladimir K. Dioumaev, P. Carroll +1 more

   201050 citations

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2. A Tungsten Complex with a Bidentate, Hemilabile N-Heterocyclic Carbene Ligand, Facile Displacement of the Weakly Bound W−(CC) Bond, and the Vulnerability of the NHC Ligand toward Catalyst Deactivation during Ketone Hydrogenation

   Fan Wu, Vladimir K. Dioumaev, D. Szalda, J. Hanson +1 more

   200748 citations

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3. Catalytic Dehydrocoupling of Phenylsilane with "Cation-like" Zirconocene Derivatives: A New Approach to Longer Silicon Chains

   Vladimir K. Dioumaev, J. Harrod

   199443 citations

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4. Synthesis and reactivity of silyl ruthenium complexes: the importance of trans effects in C-H activation, Si-C bond formation, and dehydrogenative coupling of silanes.

   Vladimir K. Dioumaev, L. Procopio, P. Carroll, D. H. Berry

   2003Journal of the American Chemical Society39 citations

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5. AN N-HETEROCYCLIC CARBENE AS A BIDENTATE HEMILABILE LIGAND IN W AND MO HYDROGENATION CATALYSTS: A SYNCHROTRON X-RAY DIFFRACTION AND DENSITY FUNCTIONAL THEORY STUDY

   Vladimir K. Dioumaev, D. Szalda, J. Hanson, J. Franz +1 more

   200335 citations

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6. STEREOSTRUCTURES OF LINEAR AND CYCLIC POLYPHENYLSILANES PRODUCED BY DEHYDROCOUPLING IN THE PRESENCE OF GROUP 4 METALLOCENE CATALYSTS

   Vladimir K. Dioumaev, K. Rahimian, F. Gauvin, J. Harrod

   199930 citations

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7. A systematic analysis of the structure-reactivity trends for some ‘cation-like’ early transition metal catalysts for dehydropolymerization of silanes

   Vladimir K. Dioumaev, J. Harrod

   199624 citations

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8. Structure and reactivity of bis(silyl) dihydride complexes (PMe(3))(3)Ru(SiR(3))(2)(H)(2): model compounds and real intermediates in a dehydrogenative C-Si bond forming reaction.

   Vladimir K. Dioumaev, B. Yoo, L. Procopio, P. Carroll +1 more

   2003Journal of the American Chemical Society23 citations

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9. Access to Unsaturated Ruthenium Complexes via Phosphine Complexation with Triphenylborane: Synthesis and Structure of a Zwitterionic Arene Complex, (η6-Ph-BPh2H)Ru(PMe3)2(SiMe3)

   Vladimir K. Dioumaev, K. Plössl, P. Carroll, D. H. Berry

   200023 citations

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10. Studies of the Formation and Decomposition Pathways for Cationic Zirconocene Hydrido Silyl Complexes

    Vladimir K. Dioumaev, J. Harrod

    199718 citations

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11. Unusual “Cation-like” Zirconocene Hydrosilyl Complex. Silylium Ligand or a Nonclassically Bonded Si−H?1

    Vladimir K. Dioumaev, J. Harrod

    199618 citations

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12. Tandem beta-C-H activation/Si-H elimination reactions: stabilization of C-H activation products by beta-agostic Si-H interactions.

    Vladimir K. Dioumaev, P. Carroll, D. H. Berry

    2003Angewandte Chemie15 citations

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13. FORMATION AND INTERCONVERSION OF RUTHENIUM-SILENE AND 16-ELECTRON RUTHENIUM SILYL COMPLEXES

    Vladimir K. Dioumaev, Karl Plössl, P. Carroll, D. H. Berry

    199914 citations

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14. Tandemβ-CH Activation/SiH Elimination Reactions: Stabilization of CH Activation Products byβ-Agostic SiH Interactions

    Vladimir K. Dioumaev, P. Carroll, D. H. Berry

    20035 citations

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