V. G. Shubin

Most-cited papers

1. Nitrenium ions: structure and reactivity

   G. Borodkin, V. G. Shubin

   200828 citations Open access

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2. Nitrenium Ions and Problem of Direct Electrophilic Amination of Aromatic Compounds

   G. Borodkin, V. G. Shubin

   200526 citations

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3. Interaction of acetonitrile with trifluoromethanesulfonic acid: unexpected formation of a wide variety of structures.

   G. E. Salnikov, A. Genaev, V. Vasiliev, V. G. Shubin

   2012Organic and biomolecular chemistry25 citations

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4. Electrophilic fluorination of aromatic compounds with NF type reagents: kinetic isotope effects and mechanism

   G. Borodkin, P. Zaikin, V. G. Shubin

   200622 citations

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5. Electrophilic reactions of aromatic and heteroaromatic compounds in ionic liquids

   G. Borodkin, V. G. Shubin

   200617 citations

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6. Solvent‐Free Fluorination of Electron‐Rich Aromatic Compounds with F‐TEDA‐BF4: Toward “Dry” Processes

   P. Zaikin, O. Dyan, D. V. Evtushok, A. Usoltsev +3 more

   201715 citations

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7. The selectivity problem in electrophilic fluorination of aromatic compounds

   G. Borodkin, V. G. Shubin

   201015 citations Open access

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8. Fluorination of aromatic compounds with N-fluorobenzenesulfonimide under solvent-free conditions

   R. Andreev, G. Borodkin, V. G. Shubin

   200914 citations

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9. Mechanism of electrophilic fluorination of aromatic compounds with NF-reagents

   G. Borodkin, P. A. Zaikin, M. M. Shakirov, V. G. Shubin

   200712 citations

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10. Noncatalytic bromination of benzene: A combined computational and experimental study

    A. Shernyukov, A. Genaev, G. E. Salnikov, H. Rzepa +1 more

    2016Journal of Computational Chemistry11 citations Open access

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11. Nitrosonium cation in chemical and biochemical reactions: achievements and prospects

    G. Borodkin, V. G. Shubin

    201710 citations Open access

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12. Study on selectivity in the reaction of 2-substituted pyridinium-N-imines with dimethyl acetylenedicarboxylate

    Vyacheslav I Supranovich, A. Vorob’ev, G. Borodkin, Yury V. Gatilov +1 more

    20169 citations

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13. Electrophilic Amination of Methylbenzenes with the System NaN3-AlCl3-HCl. Effects of the Solvent, Crown Ether, and Substrate Structure

    G. Borodkin, Innokenty R. Elanov, S. Popov, L. M. Pokrovskii +1 more

    20039 citations

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14. Quantum-chemical study of nitrosonium complexes of monocyclic aromatic compounds

    R. Andreev, G. Borodkin, V. G. Shubin

    20118 citations

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15. Eco-Friendly Fluorination of Aromatic Compounds with F-TEDA-BF 4 Reagent in Water

    G. Borodkin, P. Zaikin, V. G. Shubin

    20117 citations

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16. Electrophilic amination of methylbenzenes with sodium azide in trifluoromethanesulfonic acid

    G. Borodkin, I. R. Elanov, V. G. Shubin

    20097 citations

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17. Energy barriers to carousel rearrangements of carbocations: Quantum-chemical calculations vs. experiment

    A. Genaev, G. E. Sal'nikov, V. G. Shubin

    20077 citations

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18. Degenerate rearrangement of detectable 9,10-dimethyl-9-vinyl-phenanthrenium ion: 1,2-Shift of the vinyl group

    V. A. Bushmelev, A. Genaev, V. G. Shubin

    20067 citations

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19. Nitrosonium complexes of [2.2]paracyclophane

    G. Borodkin, Innokenty R. Elanov, R. Andreev, M. M. Shakirov +1 more

    20067 citations

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20. First example of using a ionic liquid in electrophilic amination of arenes. Amination of methylbenzenes with the system NaN3-AlCl3-HCl

    G. Borodkin, I. R. Elanov, V. G. Shubin

    20047 citations

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21. Carbocationic Cyclizations: IX. Rearrangement of Long-Lived 4-(2-Biphenylyl)-1,2,3,4-tetramethylcyclobutenyl Cation into trans- and cis-4,5,6,6-Tetramethyl-4,5,6-trihydrocyclopenta[j,k]phenanthren-5-yl Cations

    V. A. Bushmelev, A. Genaev, S. A. Osadchii, M. M. Shakirov +1 more

    20037 citations

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22. Electrophilic Fluorination of Heterocyclic Compounds with NF Reagents in Unconventional Media

    G. Borodkin, V. G. Shubin

    2022Chemistry of Heterocyclic Compounds6 citations

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23. New approach toward the synthesis of deuterated pyrazolo[1,5-a]pyridines and 1,2,4-triazolo[1,5-a]pyridines

    A. Vorob’ev, Vyacheslav I Supranovich, G. Borodkin, V. G. Shubin

    2017Beilstein Journal of Organic Chemistry6 citations Open access

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24. Degenerate rearrangement of long-lived 9-cyclopropyl-9,10-dimethyl-9,10-dihydrophenanthren-9-ylium: Migration of cyclopropyl group

    A. Genaev, G. E. Sal'nikov, V. G. Shubin

    20106 citations

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25. Fluorination of Bi- and polycyclic aromatic hydrocarbons with N-fluorobis(phenylsulfonyl)amine in the absence of solvent

    G. Borodkin, I. R. Elanov, V. G. Shubin

    20106 citations

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26. Molecular and crystal structure of 1-amino-X-pyrazinium mesitylenesulfonates

    R. Andreev, G. Borodkin, A. Y. Vorob’ev, Yury V. Gatilov +1 more

    20086 citations

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27. Degenerate Rearrangement of Long-Lived 9,10-Dimethyl-9-(cis-1-methyl-1-propenyl)phenanthrenium Ion: 1,2-Shift of the Dimethylvinyl Group

    V. A. Bushmelev, A. Genaev, V. G. Shubin

    20046 citations

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28. Structure and Reactivity of the 1,10-Phenanthroline Complex with Nitrenium Cation

    R. Andreev, G. Borodkin, Y. Gatilov, M. M. Shakirov +1 more

    20046 citations

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29. Solvent Effects in the Electrophilic Amination of Mesitylene with the System NaN3-AlCl3-HCl

    G. Borodkin, S. Popov, L. M. Pokrovskii, V. G. Shubin

    20036 citations

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30. Direct electrophilic fluorination of naproxen with NF-reagents

    G. Borodkin, I. R. Elanov, Yury V. Gatilov, V. G. Shubin

    20195 citations

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31. Progress and prospects in the use of photocatalysis for the synthesis of organofluorine compounds

    G. Borodkin, V. G. Shubin

    2019Russian Chemical Reviews5 citations Open access

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32. Unexpected cleavage of the Cpy–Cpy bond in the reaction of 2,2′-bipyridine N,N′-diimines with acetylenes

    Vyacheslav I Supranovich, G. Borodkin, A. Vorob’ev, V. G. Shubin

    20145 citations

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33. Migration of methylethynyl group in a long-lived carbocation.

    G. E. Salnikov, A. Genaev, V. A. Bushmelev, V. G. Shubin

    2013Organic and biomolecular chemistry5 citations

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34. Quantum-chemical study on uracil and thymine nitrosonium complexes

    R. Andreev, G. Borodkin, V. G. Shubin

    2012Russian journal of organic chemistry5 citations

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35. Long-lived 9-cyano-9,10-dimethylphenanthrenyl cation. Migration of cyano group in carbocations

    V. A. Bushmelev, A. Genaev, G. E. Sal'nikov, V. G. Shubin

    20115 citations

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36. Improvement of ways to obtain ethidium bromide and synthesis of ethidium ethyl sulfate, a new fluorescent dye for detection of nucleic acids

    S. A. Osadchii, V. G. Shubin, L. Kozlova, V. S. Varlamenko +2 more

    20115 citations

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37. Degenerate rearrangement of 9-isopropenyl-9,10-dimethyl-phenanthren-9-yl and 9,10-dimethyl-9-(trans-1-methylprop-1-en-1-yl)phenanthren-9-yl cations

    V. G. Artamoshkin, V. A. Bushmelev, A. Genaev, V. G. Shubin

    20065 citations

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38. Lewis Acid Effects in Mesitylene Amination in the System NaN3MHlgnHCl

    I. Borodkin, A. Bessonov, R. Andreev, V. G. Shubin

    20045 citations

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39. Regioselectivity in the amination of azines. Reaction of 1,10-phenanthroline derivatives with O-mesitylsulfonylhydroxylamine

    R. Andreev, G. Borodkin, M. M. Shakirov, V. G. Shubin

    20045 citations

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40. Reaction of Nitrosonium Tetrafluoroborate with Nitroxyl Radicals

    G. Borodkin, Innokenty R. Elanov, M. M. Shakirov, V. G. Shubin

    20035 citations

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41. Promotional effect of ionic liquids in electrophilic fluorination of methylated uracils

    G. Borodkin, I. R. Elanov, Yury V. Gatilov, V. G. Shubin

    20164 citations

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42. Electrophilic fluorination of 6-methyl- and 1,3,6-trimethyluracils in water

    G. Borodkin, Innokenty R. Elanov, V. G. Shubin

    2015Russian journal of organic chemistry4 citations

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43. Eco-friendly fluorination of 6-methyl- and 1,3,6-trimethyluracils in water

    G. Borodkin, Innokenty R. Elanov, V. G. Shubin

    2014Russian journal of organic chemistry4 citations

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44. Structure of long-lived alkynyl-substituted carbocations of the phenanthrene series and their precursors

    V. A. Bushmelev, A. Genaev, G. E. Sal'nikov, V. G. Shubin

    2013Russian journal of organic chemistry4 citations

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45. Quantum-chemical study on nitrosonium complexes of Bi- and polycyclic aromatic compounds

    R. Andreev, G. Borodkin, V. G. Shubin

    2012Russian journal of organic chemistry4 citations

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46. Reaction of 10,10-dimethyl-9-trimethylsiloxy-9,10-dihydrophenanthrene-9-carbonitrile with acids

    V. A. Bushmelev, A. Genaev, G. E. Sal'nikov, V. G. Shubin

    20114 citations

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47. Structural nonrigidity of 9,9,10-trimethyland 4,5,9,9,10-pentamethylphenanthrenylium ions

    V. A. Bushmelev, A. Genaev, G. E. Sal'nikov, V. G. Shubin

    20104 citations

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48. Energy barriers to degenerate rearrangements of long-lived carbocations: Quantum chemical calculations vs. experiment

    A. Genaev, V. G. Shubin

    20064 citations

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49. 1,3-Dipolar cycloaddition of cyanopyridines to heterocyclic N-imines: experimental and theoretical study

    A. Vorob’ev, G. Borodkin, R. Andreev, V. G. Shubin

    2021Chemistry of Heterocyclic Compounds3 citations

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50. Elevated reaction order of 1,3,5-tri-tert-butylbenzene bromination as evidence of a clustered polybromide transition state: a combined kinetic and computational study.

    A. Shernyukov, A. Genaev, G. E. Salnikov, V. G. Shubin +1 more

    2019Organic and biomolecular chemistry3 citations

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