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M. Cowie · SciRah

Researcher profile · Semantic Scholar

M. Cowie

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M. Cowie — researcher profile on SciRah

h-index: 29
Works: 194
Citations: 3,382

Most-cited papers

A NEW METHODOLOGY THAT SURPASSES CURRENT BRIDGING THEORIES TO EFFICIENTLY SEAL A VARIED PORE THROAT DISTRIBUTION AS FOUND IN NATURAL RESERVOIR FORMATIONS
S. R. Vickers, M. Cowie, T. Jones, A. Twynam
2006104 citations
Semantic Scholar
Unsymmetrical Dicarbenes Based on N-Heterocyclic/Mesoionic Carbene Frameworks: A Stepwise Metalation Strategy for the Generation of a Dicarbene-Bridged Mixed-Metal Pd/Rh Complex
Matthew T. Zamora, Michael J. Ferguson, R. McDonald, M. Cowie
201266 citations
Semantic Scholar
Di-Mesoionic Carbene-Bridged Complexes of Rh2, Ir2, and RhIr: A Stepwise Metalation Strategy for the Synthesis of di-MIC-Bridged Mixed-Metal Systems
Matthew T. Zamora, Michael J. Ferguson, M. Cowie
201250 citations
Semantic Scholar
Carbene-anchored/pendent-imidazolium species as precursors to di-N-heterocyclic carbene-bridged mixed-metal complexes.
Matthew T. Zamora, Michael J. Ferguson, R. McDonald, M. Cowie
2009Dalton Transactions42 citations
Semantic Scholar
Carbon-fluorine bond activation in fluoroolefins: clear documentation of cooperative C-F bond activation by adjacent metal centers.
D. Anderson, R. McDonald, M. Cowie
2007Angewandte Chemie38 citations
Semantic Scholar
Bridging Methylene to Bridging Acyl Conversion in Heterobinuclear Rh/Ru Complexes: Models for Adjacent-Metal Involvement in Bimetallic Catalysts
Bryan D. Rowsell, R. McDonald, M. Cowie
200433 citations
Semantic Scholar
A-Frame Complexes of Dirhodium Bridged by Dicarbene and Diphosphine Ligands
Kyle D. Wells, Michael J. Ferguson, R. McDonald, M. Cowie
200832 citations
Semantic Scholar
2003 alcan award lecture : Roles of the adjacent metals in the coupling of methylene groups promoted by heterobinuclear complexes of group 8 and 9 metals
M. Cowie
200531 citations
Semantic Scholar
Metal−Metal Cooperativity Effects in Promoting C−H Bond Cleavage of a Methyl Group by an Adjacent Metal Center
J. Torkelson, Frederick H. Antwi-Nsiah, R. McDonald, M. Cowie +3 more
199930 citations
Semantic Scholar
The bridged binding mode as a new, versatile template for the selective activation of carbon-fluorine bonds in fluoroolefins: activation of trifluoroethylene.
M. Slaney, D. Anderson, Michael J. Ferguson, R. McDonald +1 more
2010Journal of the American Chemical Society29 citations
Semantic Scholar
Polymeric ruthenium(I) and binuclear ruthenium(I) and osmium(I) carboxylate-bridged complexes containing diphoshine, diarsine, arsinophosphine, diphosphine chalcogenide, and dithioether ligands: the structure of [Ru2(CO)4(.mu.-O2CMe)2(MeSCH2SMe)]2.cntdot.THF
R. W. Hilts, S. Sherlock, M. Cowie, E. Singleton +1 more
199028 citations
Semantic Scholar
REACTIONS OF TRIETHYLAMMONIUM SALTS OF THE (MU -CO)(MU -RS)FE2(CO)6- ANIONS WITH ALKYNYLMERCURY COMPOUNDS. UNEXPECTED PRODUCTS VIA HYDROGEN MIGRATION PROCESSES
D. Seyferth, D. Ruschke, W. M. Davis, M. Cowie +1 more
199427 citations
Semantic Scholar
Phosphine–Amido Complexes of Ruthenium and Mechanistic Implications for Ketone Transfer Hydrogenation Catalysis
Lindsay J. Hounjet, Michael J. Ferguson, M. Cowie
2011Figshare25 citations Open access
Semantic Scholar
Binuclear Complexes as Models for Adjacent-Metal Involvement in C−H Bond-Cleavage and C−C Bond-Formation Steps Relevant to Fischer−Tropsch Chemistry
J. Torkelson, R. McDonald, M. Cowie
199825 citations
Semantic Scholar
Bis(diethylphosphino)methane As a Bridging Ligand in Complexes of Ir2, Rh2, and IrRh: Geminal C–H Activation of α-Olefins
M. Slaney, D. Anderson, Michael J. Ferguson, R. McDonald +1 more
201224 citations
Semantic Scholar
Methylene-to-Acetyl Conversion in Heterobinuclear Rh/Os Complexes: Models for Oxygenate Formation by Bimetallic Fischer−Tropsch Catalysts
S. Trepanier, R. McDonald, M. Cowie
200324 citations
Semantic Scholar
Methylene-Bridged Complexes of Rhodium/Ruthenium as Models for Bimetallic Fischer−Tropsch Catalysts: Comparisons with the Rh/Os and Ir/Ru Analogues
Bryan D. Rowsell, S. Trepanier, R. Lam, R. McDonald +1 more
200224 citations
Semantic Scholar
Methylene-Bridged Heterobinuclear Complexes of Iridium and Ruthenium: Models for Bimetallic Fischer−Tropsch Catalysts
M. Dell'Anna, S. Trepanier, R. McDonald, M. Cowie
200123 citations
Semantic Scholar
Coordinatively diverse ortho-phosphinoaniline complexes of ruthenium and isolation of a putative intermediate in ketone transfer hydrogenation catalysis.
Lindsay J. Hounjet, Matthias Bierenstiel, Michael J. Ferguson, R. McDonald +1 more
2010Inorganic Chemistry22 citations
Semantic Scholar
Bridging Methylene and Methyl Complexes of Rhodium/Osmium: Influence of the Ancillary Ligands on the Methyl Binding Mode
James R. Wigginton, S. Trepanier, R. McDonald, Michael J. Ferguson +1 more
200522 citations
Semantic Scholar
Carbon−Carbon Bond Formation Promoted by Adjacent Metal Centers: Regioselective Alkyne Insertions into a “Rh(μ-CH2)Ru” Moiety Yielding C3- and C5-Bridged Fragments
Bryan D. Rowsell, R. McDonald, Michael J. Ferguson, M. Cowie
200322 citations
Semantic Scholar
Reactions of triethylammonium salts of the [(.mu.-CO)(.mu.-RS)Fe2(CO)6]- anion with alkyl-, aryl-, and vinylmercuric halides. Formal C-alkylation of the bridging CO ligand
D. Seyferth, C. M. Archer, D. Ruschke, M. Cowie +1 more
199122 citations
Semantic Scholar
Binuclear alkyl complexes: Unusual ethylene adducts and facile C-H activation of a methyl group by an adjacent metal
Frederick H. Antwi-Nsiah, M. Cowie
199221 citations
Semantic Scholar
Tandem C–F and C–H Bond Activation in Fluoroolefins Promoted by a Bis(diethylphosphino)methane-Bridged Diiridium Complex: Role of Water in the Activation Processes
M. Slaney, Michael J. Ferguson, R. McDonald, M. Cowie
201219 citations
Semantic Scholar
Selective coupling of methylene groups at a Rh/Os core, yielding C2, C3, or C4 fragments: roles of the adjacent metals in carbon-carbon bond formation.
S. Trepanier, James N. L. Dennett, B. T. Sterenberg, R. McDonald +1 more
2004Journal of the American Chemical Society19 citations
Semantic Scholar
Binuclear Fluorovinyl Complexes of Iridium: Transformation of an Iridium-Bound Trifluorovinyl Group into a trans-[Ir−C(F)C(F)CH3] Moiety
D. Ristic-Petrovic, Mei-Tian Wang, R. McDonald, M. Cowie
200219 citations
Semantic Scholar
S-H Bond Activation in H2S and Thiols by[RhMn(CO)4(Ph2PCH2PPh2)2]. Compounds Containing Terminal or Bridging Sulfhydryl and Thiolato Groups
Li-Sheng Wang, R. McDonald, M. Cowie
199419 citations
Semantic Scholar
Structure and reactivity studies of the unusual peroxo-bridged iridium complex, [Ir2I2(CO)2(.mu.-O2)(Ph2PCH2PPh2)2]: the first compound having a peroxide moiety bridging a metal-metal bond
Jian-Liang Xiao, B. Santarsiero, B. Vaartstra, M. Cowie
199319 citations
Semantic Scholar
Sulfur-hydrogen and selenium-hydrogen bond activation by both metal centers in [MM[prime](CO)[sub 3](Ph[sub 2]PCH[sub 2]PPh[sub 2])[sub 2]] (M, M[prime] = Rh, Ir)
R. McDonald, M. Cowie
199319 citations
Semantic Scholar
A convenient general route to a series of diphosphine-bridged heterobinuclear complexes that contain rhodium and structures of the mixed-valent complexes [RhM(CO)4(Ph2PCH2PPh2)2] (M=Mn, Re)
D. Antonelli, M. Cowie
199019 citations
Semantic Scholar
Alkyne/methylene coupling reactions at adjacent Rh/Os centers : Stepwise transformations from C1- through C4-bridged species
James R. Wigginton, Amala Chokshi, Todd W. Graham, R. McDonald +2 more
200518 citations
Semantic Scholar
((Diaryl- and Dialkylphosphino)alkyl)cyclopentadienyl Ligands and Their Use in the Preparation of Heterobinuclear Ti/Mo and Zr/Mo Complexes
Todd W. Graham, A. Llamazares, R. McDonald, M. Cowie
199918 citations
Semantic Scholar
Heterobinuclear Vinyl, Allyl, and Related Complexes of Rhodium/Osmium from Terminal Alkynes and Allenes, Vinyl to Carbene Transformations, and the Structures of [RhOs(C(CH3)CH2)(CO)3(Ph2PCH2PPh2)2] and [RhOs(C(CH3)C(CH3)2)(CH3)(CO)3(Ph2PCH2PPh2)2][CF3SO3]
B. T. Sterenberg, R. McDonald, M. Cowie
199718 citations
Semantic Scholar
HETEROBINUCLEAR ALKYL COMPLEXES OF RHODIUM AND IRIDIUM. MIGRATORY INSERTION OR IR-TO-RH MIGRATION OF A METHYL GROUP IN REACTIONS WITH SMALL MOLECULES
Frederick H. Antwi-Nsiah, Okemona Oke, M. Cowie
199618 citations
Semantic Scholar
Reactions of 2-furyl, 2-thienyl, and N-methyl-2-pyrrolyl mercurials with [Et3NH][(.mu.-CO)(.mu.-RS)Fe2(CO)6] complexes. Synthesis of Fe2(CO)6 complexes with bridging .eta.1:.eta.2-furyl and thienyl ligands
D. Seyferth, L. Anderson, F. Villafañe, M. Cowie +1 more
199218 citations
Semantic Scholar
Comparison of structure and reactivity of phosphine-amido and hemilabile phosphine-amine chelates of rhodium.
Lindsay J. Hounjet, R. McDonald, Michael J. Ferguson, M. Cowie
2011Inorganic Chemistry17 citations
Semantic Scholar
Unsymmetrically Bridged Methyl Groups as Intermediates in the Transformation of Bridging Methylene to Bridging Acetyl Groups: Ligand Migrations and Migratory Insertions in Mixed Iridium/Ruthenium Complexes
Rahul G. Samant, S. Trepanier, James R. Wigginton, Li Xu +4 more
200917 citations
Semantic Scholar
Heterobinuclear Hydrido, Alkyl, and Related Complexes of Rh/Os. Site-Specific Reductive Elimination of Methane from a Rh/Os Core and the Structures of [RhOs(CH2CN)(CO)3(dppm)2] and [RhOs(CH3)(CO)3(dppm)2]
B. T. Sterenberg, R. W. Hilts, G. Moro, R. McDonald +1 more
199517 citations
Semantic Scholar
Binuclear oxidative additions of silanes to [Ir2(CO)3(Ph2PCH2PPh2)2] to yield silylene-bridged dihydride complexes
R. McDonald, M. Cowie
199017 citations
Semantic Scholar
Diphosphine-bridged heterobimetallic hydride and carbonyl complexes of rhodium and iridium. Structure of [RhIr(CO)3(Ph2PCH2PPh2)2], a complex containing an Ir(-I) .fwdarw. Rh(I) dative bond
R. McDonald, M. Cowie
199017 citations
Semantic Scholar
Reactions of the Binuclear Complexes [MIr(CO)3(Ph2PCH2PPh2)2] (M = Rh, Ir) with Alkyl Halides: Dramatic Reactivity Differences as a Function of Metal Combination and Alkyl Halide
J. Torkelson, Okemona Oke, J. Muritu, R. McDonald +1 more
200016 citations
Semantic Scholar
Multiple silicon-hydrogen bond activations at adjacent rhodium and iridium centers.
Md Hosnay Mobarok, Okemona Oke, Michael J. Ferguson, R. McDonald +1 more
2010Inorganic Chemistry15 citations
Semantic Scholar
Binuclear activation of cumulenes : Roles of the adjacent metals and the cumulene binding mode in the activation process
D. Ristic-Petrovic, D. Anderson, J. Torkelson, Michael J. Ferguson +2 more
200515 citations
Semantic Scholar
Olefin Binding in a Binuclear Iridium Complex as a Function of Fluorine Substitution: Ethylene to Tetrafluoroethylene
D. Ristic-Petrovic, D. Anderson, J. Torkelson, R. McDonald +1 more
200315 citations
Semantic Scholar
Double Activation of the Geminal Carbon−Hydrogen Bonds in 1,3-Butadiene by a Diiridium Complex
D. Ristic-Petrovic, J. Torkelson, R. W. Hilts, R. McDonald +1 more
200015 citations
Semantic Scholar
Diverse Reactivity of Alkynes with the Binuclear Methyl and Incipient Methyl Complexes [RhIr(CH3)(CO)3(Ph2PCH2PPh2)2][CF3SO3] and [Ir2H(CO)3(μ-CH2)(Ph2PCH2PPh2)2][CF3SO3]
Frederick H. Antwi-Nsiah, Okemona Oke, M. Cowie
199615 citations
Semantic Scholar
BRIDGING VINYLIDENE COMPLEXES OF RHMN AND EVIDENCE FOR MIGRATORY INSERTIONS TO GIVE TERMINAL VINYL GROUPS
Li-Sheng Wang, M. Cowie
199515 citations
Semantic Scholar
Synthesis and reactions of the [(.mu.-Ph2P)Fe2(CO)6]- anion
D. Seyferth, K. Brewer, Timothy G. Wood, M. Cowie +1 more
199215 citations
Semantic Scholar
Dithiophosphinate-bridged ruthenium(I) and ruthenium(II) complexes. The structure of [(Ru2(CO)4(.mu.-S2PMe2)2(PPh3)2].cntdot.1/2CH2Cl2
R. W. Hilts, M. Cowie
199015 citations
Semantic Scholar
Germyl- and germylene-bridged complexes of Rh/Ir and subsequent chemistry of a bridging germylene group.
Md Hosnay Mobarok, R. McDonald, Michael J. Ferguson, M. Cowie
2012Inorganic Chemistry14 citations
Semantic Scholar

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