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Alexandra Velian · SciRah

Researcher profile · Semantic Scholar

Alexandra Velian

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Alexandra Velian — researcher profile on SciRah

h-index: 16
Works: 44
Citations: 1,153

Most-cited papers

Arene non-innocence in dinuclear complexes of Fe, Co, and Ni supported by a para-terphenyl diphosphine.
Kyle T. Horak, Alexandra Velian, Michael W. Day, T. Agapie
2014Chemical Communications229 citations Open access
Semantic Scholar
Synthesis and C-C coupling reactivity of a dinuclear Ni(i)-Ni(i) complex supported by a terphenyl diphosphine.
Alexandra Velian, Sibo Lin, Alexander J. M. Miller, Michael W. Day +1 more
2010Journal of the American Chemical Society132 citations
Semantic Scholar
Synthesis and characterization of P2N3−: An aromatic ion composed of phosphorus and nitrogen
Alexandra Velian, C. Cummins
2015Science95 citations
Semantic Scholar
Facile synthesis of dibenzo-7λ3-phosphanorbornadiene derivatives using magnesium anthracene.
Alexandra Velian, C. Cummins
2012Journal of the American Chemical Society78 citations
Semantic Scholar
Mechanism and Scope of Phosphinidene Transfer from Dibenzo-7-phosphanorbornadiene Compounds.
Wesley J. Transue, Alexandra Velian, M. Nava, Cristina García-Iriepa +2 more
2017Journal of the American Chemical Society74 citations Open access
Semantic Scholar
Building Diatomic and Triatomic Superatom Molecules.
Anouck M. Champsaur, Alexandra Velian, D. Paley, Bonnie Choi +3 more
2016Nano letters (Print)63 citations
Semantic Scholar
A retro Diels-Alder route to diphosphorus chemistry: molecular precursor synthesis, kinetics of P2 transfer to 1,3-dienes, and detection of P2 by molecular beam mass spectrometry.
Alexandra Velian, M. Nava, M. Temprado, Yan Zhou +2 more
2014Journal of the American Chemical Society60 citations
Semantic Scholar
Dipalladium(I) Terphenyl Diphosphine Complexes as Models for Two-Site Adsorption and Activation of Organic Molecules
Sibo Lin, David E. Herbert, Alexandra Velian, Michael W. Day +1 more
2013Journal of the American Chemical Society51 citations Open access
Semantic Scholar
Thermodynamic and kinetic study of cleavage of the N-O bond of N-oxides by a vanadium(III) complex: enhanced oxygen atom transfer reaction rates for adducts of nitrous oxide and mesityl nitrile oxide.
Taryn D. Palluccio, E. Rybak-Akimova, Subhojit Majumdar, Xiaochen Cai +9 more
2013Journal of the American Chemical Society37 citations
Semantic Scholar
A Molecular Precursor to Phosphaethyne and Its Application in Synthesis of the Aromatic 1,2,3,4-Phosphatriazolate Anion.
Wesley J. Transue, Alexandra Velian, M. Nava, M. Martin-Drumel +7 more
2016Journal of the American Chemical Society34 citations Open access
Semantic Scholar
Surface Modification of Black Phosphorus with Group 13 Lewis Acids for Ambient Protection and Electronic Tuning.
D. Tofan, Yuka Sakazaki, Kendahl L. Walz Mitra, Ruoming Peng +3 more
2021Angewandte Chemie32 citations
Semantic Scholar
Metal-Support Interactions in Molecular Single-Site Cluster Catalysts.
B. S. Mitchell, A. Chirila, Jonathan A. Kephart, Andrew C Boggiano +4 more
2022Journal of the American Chemical Society25 citations Open access
Semantic Scholar
Hydroalkylation of Alkynes: Functionalization of the Alkenyl Copper Intermediate through Single Electron Transfer Chemistry
Avijit Hazra, Jonathan A. Kephart, Alexandra Velian, G. Lalic
2021Journal of the American Chemical Society25 citations Open access
Semantic Scholar
Synthesis of a diniobium tetraphosphorus complex by a 2(3−1) process
Alexandra Velian, C. Cummins
201223 citations
Semantic Scholar
Surface Functionalization of Black Phosphorus with Nitrenes: Identification of P=N Bonds Using Isotopic Labeling.
Kendahl L. Walz Mitra, Christine H. Chang, Michael P. Hanrahan, Jia-Ying Yang +6 more
2020Angewandte Chemie22 citations Open access
Semantic Scholar
Atomically Defined Nano-Propeller Fe3Co6Se8(Ph2PNTol)6: Functional Model for the Electronic Metal-Support Interaction Effect, and High Catalytic Activity for Carbodiimide Formation.
Jonathan A. Kephart, B. S. Mitchell, A. Chirila, K. Anderton +3 more
2019Journal of the American Chemical Society22 citations
Semantic Scholar
Informed Chemical Classification of Organophosphorus Compounds via Unsupervised Machine Learning of X-ray Absorption Spectroscopy and X-ray Emission Spectroscopy.
Samantha Tetef, Vikram Kashyap, W. M. Holden, Alexandra Velian +2 more
2022Journal of Physical Chemistry A16 citations Open access
Semantic Scholar
The stannylphosphide anion reagent sodium bis(triphenylstannyl) phosphide: synthesis, structural characterization, and reactions with indium, tin, and gold electrophiles.
C. Cummins, Chao Huang, T. J. Miller, Markus W. Reintinger +6 more
2014Inorganic Chemistry15 citations
Semantic Scholar
Redox-Switchable Allosteric Effects in Molecular Clusters
B. S. Mitchell, Sebastian M. Krajewski, Jonathan A. Kephart, Dylan Rogers +2 more
2021JACS Au14 citations Open access
Semantic Scholar
Multi-active Site Dynamics on a Molecular Cr/Co/Se Cluster Catalyst.
Jonathan A. Kephart, B. S. Mitchell, W. Kaminsky, Alexandra Velian
2022Journal of the American Chemical Society13 citations Open access
Semantic Scholar
Synthesis, Characterization, and Thermolysis of Dibenzo-7-dimethylgermanorbornadiene
Alexandra Velian, Wesley J. Transue, C. Cummins
201512 citations
Semantic Scholar
Conformations of cyclopentasilane stereoisomers control molecular junction conductance
Haixing Li, M. H. Garner, Zhichun Shangguan, Qianwen Zheng +9 more
2016Chemical Science11 citations Open access
Semantic Scholar
Role of axial base coordination in isonitrile binding and chalcogen atom transfer to vanadium(III) complexes.
Subhojit Majumdar, Julia M. Stauber, Taryn D. Palluccio, Xiaochen Cai +6 more
2014Inorganic Chemistry11 citations
Semantic Scholar
Tuning the Electronic Structure of Atomically Precise Sn/Co/Se Nanoclusters via Redox Matching of Tin(IV) Surface Sites.
B. S. Mitchell, W. Kaminsky, Alexandra Velian
2021Inorganic Chemistry9 citations
Semantic Scholar
Caught in the Act of Substitution: Interadsorbate Effects on an Atomically Precise Fe/Co/Se Nanocluster
Jonathan A. Kephart, Daniel Y. Zhou, J. Sandwisch, Nathalia Cajiao +6 more
2024ACS Central Science8 citations Open access
Semantic Scholar
Interstellar Chemistry in a Glovebox: Elusive Diatomic P≡N, Exposed
D. Tofan, Alexandra Velian
2020ACS Central Science8 citations Open access
Semantic Scholar
Hierarchical nanosheets built from superatomic clusters: properties, exfoliation and single-crystal-to-single-crystal intercalation
Jonathan A. Kephart, Catherine G Romero, Chun-Chih Tseng, K. Anderton +3 more
2020Chemical Science8 citations Open access
Semantic Scholar
Surface Functionalization of Black Phosphorus with Nitrenes: Identification of P=N Bonds by Using Isotopic Labeling
Kendahl L. Walz Mitra, Christine H. Chang, Michael P. Hanrahan, Jia-Ying Yang +6 more
Angewandte Chemie7 citations
Semantic Scholar
Exploring Charge Redistribution at the Cu/Co6Se8 Interface.
Sebastian M Krajewski, R. Love, Jonathan A. Kephart, Andrew C Boggiano +3 more
2024Inorganic Chemistry4 citations
Semantic Scholar
Reaction Chemistry at Discrete Organometallic Fragments on Black Phosphorus.
Kendahl L. Walz-Mitra, Michael Riehs, Andrei Draguicevic, William A. Swann +2 more
2023Angewandte Chemie4 citations
Semantic Scholar
Assembly and stabilization of {E(cyclo-P3)2} (E = Sn, Pb) as a bridging ligand spanning two triaryloxyniobium units.
Alexandra Velian, B. Cossairt, C. Cummins
2016Dalton Transactions4 citations
Semantic Scholar
Probing Edge/Support Electronic Cooperativity in Single Edge Fe/Co6Se8 Clusters.
B. S. Mitchell, A. Chirila, K. Anderton, W. Kaminsky +1 more
2023Inorganic Chemistry3 citations Open access
Semantic Scholar
Metal/Support Interactions Regulate Substrate Binding in Fe/Co/Se Cluster Catalysts.
B. S. Mitchell, A. Chirila, Daniel Y. Zhou, Jonathan A. Kephart +1 more
2023Inorganic Chemistry3 citations Open access
Semantic Scholar
Taming reactive phosphorus intermediates with organic and inorganic carriers
Alexandra Velian
20153 citations
Semantic Scholar
Molecular Plasmonic Cavities.
D. J. Rizzo, Michael Riehs, Hang Liu, Dongbin Shin +5 more
2025Nano letters (Print)2 citations Open access
Semantic Scholar
Inorganic clusters as metalloligands: ligand effects on the synthesis and properties of ternary nanopropeller clusters.
Jonathan A. Kephart, Andrew C Boggiano, W. Kaminsky, Alexandra Velian
2020Dalton Transactions2 citations
Semantic Scholar
Dual Metal Complex Functionalization of Black Phosphorus.
Andrei Draguicevic, G. Ren, Lauren Peck, Orlando Salguero +3 more
2026Nano letters (Print)1 citations Open access
Semantic Scholar
Tuning the Electronic Properties of Black Phosphorus through Surface Functionalization and Mechanical Strain for Interfacial Hydrogen Evolution Reactions
Natacha Oget, Michael Riehs, Mitchell E. Kaiser, Hao Tang +2 more
2026ECS Meeting Abstracts0 citations
Semantic Scholar
Impact of chalcogen identity on the properties of Fe/Co/Ch clusters.
R. Love, Werner Kaminsky, Alexandra Velian
2026Chemical Communications0 citations Open access
Semantic Scholar
Redox-Dependent Intersite Coupling in Fe/Co/Se Clusters
Daniel Y. Zhou, Jeewhan Oh, R. Love, Jonathan A. Kephart +2 more
2026Journal of the American Chemical Society0 citations
Semantic Scholar
Functionalization of Black Phosphorus with Tungsten Complexes Towards Hydrogen Evolution
Lauren Peck, Andrei Draguicevic, Alexandra Velian
2026ECS Meeting Abstracts0 citations
Semantic Scholar
Dual Metal Functionalization of Black Phosphorus Towards Molecularly Defined Single Site Catalysts
Andrei Draguicevic, G. Ren, Lauren Peck, Orlando Salguero +3 more
2026ECS Meeting Abstracts0 citations
Semantic Scholar
Synthesis and Reactivity of Iron and Cobalt Bis(amidophosphine selenide) Complexes
Daniel Y. Zhou, Kelsey S Zimmerman, Paige M. Gannon, Sebastian M Krajewski +3 more
2024Organometallics0 citations
Semantic Scholar
Exploring the Limits of Redox Cooperativity in Fe/Se/Co Nanoclusters
Alexandra Velian, Daniel Y. Zhou
2023ACS Fall 2023 - San Francisco, California, United States of America - August - 20230 citations Open access
Semantic Scholar

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