(Acetato-κO)(acetato-κO,O′)bis(1,3-diazinane-2-thione-κS)cadmium(II)
Rashid Mahmooda, S. G. Hussainb, Mohammed Fettouhic, Anvarhusein Abdulkadir Isabc, Saeed Ahmadb d✉
- aDivision of Science and Technology, University of Education, Township, Lahore, Pakistan
- bDepartment of Chemistry, University of Engineering and Technology, Lahore 54890, Pakistan, and
- cDepartment of Chemistry, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia
- dDepartment of Chemistry, University of Engineering and Technology, Lahore 54890, Pakistan
- ✉Corresponding author
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Abstract
In the title complex, [Cd(CH(3)COO)(2)(C(4)H(8)N(2)S)(2)], the Cd(II) cation is coordinated by three acetate O atoms and two S atoms of Diaz [Diaz = 1,3-diazinane-2-thione = 3,4,5,6-tetra-hydro-pyrimidine-2(1H)-thione]. The Cd(II) coordination is augmented by one considerably longer Cd-O bond of 2.782 (3) Å to a carboxyl-ate O atom. The resulting coordination polyhedron around the Cd(II) cations can be described as a highly distorted octa-hedron. The Diaz ligand and the acetate anions are linked by N-H⋯O hydrogen-bonding inter-actions.
TL;DRIn the title complex, [Cd(CH3COO)2(C4H8N2S)2], the CdII cation is coordinated by three acetate O atoms and two S atoms of Diaz and can be described as a highly distorted octahedron. (Semantic Scholar)