CuO-Fe2O3/calcium alginate-carboxymethylcellulose-chitosan as efficient nanocomposite beads for catalytic reduction of water pollutants
Nujud Maslamania b, Sher Bahadar Khanc, Esraa M. Bakhshc✉, Kalsoom Akhtarc, Metab Alharbid
- aDepartment of Physical Sciences, Chemistry Division, College of Science, Jazan University, P.O. Box 114, Jazan 45142, Saudi Arabia
- bNanotechnology Research Unit, College of Science, Jazan University, P.O. Box 114, Jazan 45142, Saudi Arabia
- cChemistry Department, Faculty of Science, King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi Arabia
- dDepartment of Pharmacology and Toxicology, College of Pharmacy, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia
- ✉Corresponding author
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Abstract
• Development of CuO-Fe 2 O 3 /CA-CMC-Cs nanocomposite beads. • Efficient catalyst for the reduction of nitrophenols and dyes. • Recyclability of the catalyst up to three times. This study involved the synthesis and catalytic activity testing of new nanocomposite beads (CuO-Fe 2 O 3 /CA-CMC-Cs) prepared by facile and environmentally friendly approach. CuO-Fe 2 O 3 was prepared and applied for the catalytic reduction of 4-nitrophenol (4-NP). The results showed that CuO-Fe 2 O 3 demonstrate high catalytic activity toward the reduction of 4-NP to 4-aminophenol (4-AP). Further, CuO-Fe 2 O 3 were well-dispersed in the polymeric matrix of CA-CMC-Cs to prepare CuO-Fe 2 O 3 /CA-CMC-Cs beads via crosslinker agent (AlCl 3 ). CuO-Fe 2 O 3 /CA-CMC-Cs beads were also applied for the catalytic reduction of nitrophenol isomers (4-NP, 2-NP, and 2,6-DNP), organic dyes (methyl orange (MO), eosin yellow (EY)) and potassium hexacyanoferrate (K 3 [Fe(CN) 6 ]). K 3 [Fe(CN) 6 ] was found to be effectively reduced by the beads and was completed within 30 s. While the catalytic reduction of 4-NP, EY and MO were completed within 300, 240 and 180 s and the rate constants were discovered to be 1.16 × 10 −2 s −1 , 1.68 × 10 −2 s −1 and 1.51 × 10 −2 s −1 , respectively. The CuO-Fe 2 O 3 /CA-CMC-Cs beads catalytic activity was enhanced utilizing 4-NP as a model molecule. The beads had good catalytic activity and may be reused up to three times before losing their effectiveness. Additionally, the ability of the CuO-Fe 2 O 3 /CA-CMC-Cs beads to reduce 4-NP and MO in real samples such as wastewater, orange juice and strawberry juice was investigated where the reduction percentage was 91.5 %–89.0 % in the real samples. The results demonstrated that the beads were more efficient for reduction of 4-NP and MO in milk, while, in juices required more time and had a lower reduction percentage.